{"created":"2023-05-15T12:13:43.294154+00:00","id":169,"links":{},"metadata":{"_buckets":{"deposit":"0c1662c0-912e-4d9a-ad14-5a04f3dfb6a2"},"_deposit":{"created_by":12,"id":"169","owners":[12],"pid":{"revision_id":0,"type":"depid","value":"169"},"status":"published"},"_oai":{"id":"oai:junshin.repo.nii.ac.jp:00000169","sets":["1:7:17:36"]},"author_link":["274"],"control_number":"169","item_10002_alternative_title_1":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"移動床方式ベンチスケール装置による揮発性有機塩素化合物と酸化カルシウムの脱塩素化反応","subitem_alternative_title_language":"ja"}]},"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-03-31","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"48","bibliographicPageEnd":"136","bibliographicPageStart":"129","bibliographic_titles":[{"bibliographic_title":"純真紀要"},{"bibliographic_title":"Bulletin of Junshin Junior College","bibliographic_titleLang":"en"}]}]},"item_10002_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"【Abstract】\n Dechlorinating reaction between volatile organic chlorides (VOCs) and CaO has been studied using a bench scale moving bed. CaO was very effective for dechlorinating from VOCs, but troublesome for its moisture absorption. Handling of powdered CaO was so difficult that we used 2 ~4 mm of CaO particles. CaO particles were suplied by screw feeder into the top of the moving bed. Countercurrent reaction was occurred between CaO and VOCs in the moving bed reaction tube.\n In this study, the result of review for C₂HCL₃ (trichloroetheyene,TCE) in VOCs was shown. TCE was completely changed to CaCl₂,CO₂ and H₂O at about 730℃. Inlet of the concentrations of TCE were 8.3×10³ ~ 2.4×10⁴ ppm and after the reaction, the concentrations of TCE were not detected in the off-gas. Off-gas was analyzed by gas chromatograph (GC) and gas chromatograph mass spectrometer (GC-MS). Below 650℃, a few ppm of C₂Cl₄ (perchloroethyene, PCE) was detected as a by-product. This was collected by activated harcoal layer.","subitem_description_language":"en","subitem_description_type":"Abstract"},{"subitem_description":"【要旨】\n揮発性有機塩素化合物（VOCs）と酸化カルシウム（CaO）間の脱塩素化反応を、移動床方式のベンチスケール装置を開発し、検討した。CaOはVOCsの脱塩素化に極めて効果的であったが、吸湿性を有するという問題があった。粉体CaOの扱いは極めて困難であった為、我々は粒径2～4ｍｍの粒体CaOを使用する事とした。CaO粒子はスクリューフィーダにより移動床の上部へ供給した。移動床反応塔の中でCaOとVOCsは、逆流相接触によって反応が進行した。\nこの報告は、VOCs中のC₂HCl₃（トリクロロエチレン、TCE)についての検討結果である。TCEは約730℃で完全に塩化カルシウム、二酸化炭素及び水蒸気に変化した。反応塔導入口のTCE濃度は8.3～10³～2.4×10⁴ppmであり、反応後の反応塔排気口のTCEは検出されなかった。廃棄ガスは、ガスクロマトグラフ及びガスクロマトグラフ質量分析計により分析した。650℃以下では反応副生成物として数ppmのC₂Cl₄（パークロロエチレン、PCE)が検出された。それは活性炭層に吸収された。","subitem_description_language":"ja","subitem_description_type":"Abstract"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"純真短期大学","subitem_publisher_language":"ja"}]},"item_10002_relation_12":{"attribute_name":"論文ID（NAID）","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"40016100947","subitem_relation_type_select":"NAID"}}]},"item_10002_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"純真短期大学","subitem_rights_language":"ja"}]},"item_10002_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN0011314X","subitem_source_identifier_type":"NCID"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03855651","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1710308327429":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Dechlorinating Reaction between Volatile Organic Chlorides and Calcium Oxide by Bench Scale Moving Bed","subitem_title_language":"en"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"0000 0004 0639 7440","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"https://isni.org/isni/0000000406397440"}],"affiliationNames":[{"affiliationName":"純真短期大学","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"TSUCHIYA, Yuji","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"274","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"9000010550546","nameIdentifierScheme":"CiNii ID","nameIdentifierURI":"http://ci.nii.ac.jp/nrid/9000010550546"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Dechlorinating Reaction between Volatile Organic Chlorides and Calcium Oxide by Bench Scale Moving Bed","item_type_id":"10002","owner":"12","path":["36"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-10-26"},"publish_date":"2017-10-26","publish_status":"0","recid":"169","relation_version_is_last":true,"title":["Dechlorinating Reaction between Volatile Organic Chlorides and Calcium Oxide by Bench Scale Moving Bed"],"weko_creator_id":"12","weko_shared_id":-1},"updated":"2024-06-11T07:55:36.387897+00:00"}