{"created":"2023-05-15T12:13:38.326851+00:00","id":66,"links":{},"metadata":{"_buckets":{"deposit":"a384fa8f-32f7-4a18-aace-5a5c1fdb5cfd"},"_deposit":{"created_by":12,"id":"66","owners":[12],"pid":{"revision_id":0,"type":"depid","value":"66"},"status":"published"},"_oai":{"id":"oai:junshin.repo.nii.ac.jp:00000066","sets":["1:6:88:25"]},"author_link":["100","101"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"078","bibliographicPageStart":"075","bibliographic_titles":[{"bibliographic_title":"純真学園大学雑誌"},{"bibliographic_title":"Journal of Junshin Gakuen University,Faculty of  Health Sciences","bibliographic_titleLang":"en"}]}]},"item_10002_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10002_description_6":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Abstract : Aminodiphenylamine and its derivatives have been known to be used as dye intermediates and antioxidant of rubber. This study investigated the preparation of 4-aminodiphenylamine via two step reaction in a one pot procedure. For the first step, the coupling reaction of nitrobenzene and aniline was carried out in an aqueous solution of teramethylammonium hydroxide, sodium hydroxide, and potassium hydroxide as the base.The major products of this one step reaction include nitor-, nitroso-, and diphenylamine derivatives. Azobenzene and its derivatives were by-products. The effect of catalyst on the reaction of nitrobenzene with aniline was investigated. It was also observed that the property and position of nitroarene and aminoarene substituent groups impacted product yield. Subsequently, the imtemediate product mixture without workup could be reduced with Raney Ni-Al alloy ando Al powder in a dilute aqueous alkaline solution, affording the objective aminodiphenylamine derivatives. A high yield of 4-aminodiphenylamine can be obtained in a one pot operation via aniline and nitrobenzene reactions as well as reduction of cryde nuxtyre using a Raney Ni-Al alloy and aluminum powder as the reductive agents in a dilute aqueous alkaline solution.","subitem_description_type":"Other"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"純真学園大学"}]},"item_10002_relation_12":{"attribute_name":"論文ID（NAID）","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"40019797419","subitem_relation_type_select":"NAID"}}]},"item_10002_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12581584","subitem_source_identifier_type":"NCID"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2186-6481","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nakahara, Yukiko"},{"creatorName":"Nakahara, Yukiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"100","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"9000241751264","nameIdentifierScheme":"CiNii ID","nameIdentifierURI":"http://ci.nii.ac.jp/nrid/9000241751264"}]},{"creatorNames":[{"creatorName":"Ma, Jiang"},{"creatorName":"Ma, Jiang","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"9000241751265 ","nameIdentifierScheme":"CiNii ID","nameIdentifierURI":"http://ci.nii.ac.jp/nrid/9000241751265 "}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-10-04"}],"displaytype":"detail","filename":"純真学園大学雑誌-01号_p075-078.pdf","filesize":[{"value":"141.3 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"純真学園大学雑誌-01号_p075-078","url":"https://junshin.repo.nii.ac.jp/record/66/files/純真学園大学雑誌-01号_p075-078.pdf"},"version_id":"72d19e0c-416c-44f9-bc0d-f30356ae5608"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"4-Aminodiphenylamine","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"coupling reaction","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"one-pot reaction","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Raney Ni-Al alloy","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"PREPARATION OF 4-AMINODIPHENYLAMINE BY A ONE-POT REACTION","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"PREPARATION OF 4-AMINODIPHENYLAMINE BY A ONE-POT REACTION"},{"subitem_title":"PREPARATION OF 4-AMINODIPHENYLAMINE BY A ONE-POT REACTION","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"12","path":["25"],"pubdate":{"attribute_name":"公開日","attribute_value":"2016-10-05"},"publish_date":"2016-10-05","publish_status":"0","recid":"66","relation_version_is_last":true,"title":["PREPARATION OF 4-AMINODIPHENYLAMINE BY A ONE-POT REACTION"],"weko_creator_id":"12","weko_shared_id":-1},"updated":"2023-05-15T15:47:21.600610+00:00"}