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PREPARATION OF 4-AMINODIPHENYLAMINE BY A ONE-POT REACTION
https://junshin.repo.nii.ac.jp/records/66
https://junshin.repo.nii.ac.jp/records/667295c0b8-1a4e-4840-bdd1-a81d56b0a2f2
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
純真学園大学雑誌-01号_p075-078 (141.3 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||||||||||
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| 公開日 | 2016-10-05 | |||||||||||||
| 言語 | ||||||||||||||
| 言語 | eng | |||||||||||||
| キーワード | ||||||||||||||
| 言語 | en | |||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | 4-Aminodiphenylamine | |||||||||||||
| キーワード | ||||||||||||||
| 言語 | en | |||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | coupling reaction | |||||||||||||
| キーワード | ||||||||||||||
| 言語 | en | |||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | one-pot reaction | |||||||||||||
| キーワード | ||||||||||||||
| 言語 | en | |||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | Raney Ni-Al alloy | |||||||||||||
| 資源タイプ | ||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||
| 資源タイプ | departmental bulletin paper | |||||||||||||
| 著者 |
Nakahara, Yukiko
× Nakahara, Yukiko
× Ma, Jiang
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| 内容記述 | ||||||||||||||
| 内容記述タイプ | Other | |||||||||||||
| 内容記述 | Abstract : Aminodiphenylamine and its derivatives have been known to be used as dye intermediates and antioxidant of rubber. This study investigated the preparation of 4-aminodiphenylamine via two step reaction in a one pot procedure. For the first step, the coupling reaction of nitrobenzene and aniline was carried out in an aqueous solution of teramethylammonium hydroxide, sodium hydroxide, and potassium hydroxide as the base.The major products of this one step reaction include nitor-, nitroso-, and diphenylamine derivatives. Azobenzene and its derivatives were by-products. The effect of catalyst on the reaction of nitrobenzene with aniline was investigated. It was also observed that the property and position of nitroarene and aminoarene substituent groups impacted product yield. Subsequently, the imtemediate product mixture without workup could be reduced with Raney Ni-Al alloy ando Al powder in a dilute aqueous alkaline solution, affording the objective aminodiphenylamine derivatives. A high yield of 4-aminodiphenylamine can be obtained in a one pot operation via aniline and nitrobenzene reactions as well as reduction of cryde nuxtyre using a Raney Ni-Al alloy and aluminum powder as the reductive agents in a dilute aqueous alkaline solution. | |||||||||||||
| 書誌情報 |
純真学園大学雑誌 en : Journal of Junshin Gakuen University,Faculty of Health Sciences 号 1, p. 075-078, 発行日 2012-03 |
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| 出版者 | 純真学園大学 | |||||||||||||
| ISSN | ||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||
| 収録物識別子 | 2186-6481 | |||||||||||||
| 書誌レコードID | ||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||
| 収録物識別子 | AA12581584 | |||||||||||||
| 論文ID（NAID） | ||||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||||
| 識別子タイプ | NAID | |||||||||||||
| 関連識別子 | 40019797419 | |||||||||||||
| フォーマット | ||||||||||||||
| 内容記述タイプ | Other | |||||||||||||
| 内容記述 | application/pdf | |||||||||||||
| 著者版フラグ | ||||||||||||||
| 出版タイプ | VoR | |||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||
